Browsing by Author "Oke MA"

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    Influence of nature of catalyst on biodiesel synthesis via irradiation-aided transesterification of waste cooking oil-honne seed oil blend: Modeling and optimization by Taguchi design method
    (2021) Falowo OA; Apanisile OE; Aladelusi AO; Adeleke AE; Oke MA; Enamhanye A; Latinwo LM; Betiku E
    Biodiesel synthesis from waste cooking oil (WCO) and honne (Calophyllum inophyllum) seed oil (HSO) blend with heterogeneous (calcined Ba(OH)2 and calcined biomass waste (CBW) from Enterolobium cyclocarpum) and homogeneous (KOH) catalysts via two-step irradiated-transesterification process was evaluated in this study. The modeling and optimization of the two processes were studied using Taguchi orthogonal array technique. The factors considered for the esterification process were methanol/WCO-HSO ratio (10:1–30:1), time (2–8 min), heating power (150–450 W), and H2SO4 dosage (0.5–1.5 wt%). In contrast, the factors considered for the transesterification process were methanol/WCO-HSO ratio (6:1–12:1), time (1–7 min), heating power (150–450 W), and catalyst dosage (1–2.5 wt%). Minimum FFA of 0.50% was attained using methanol/WCO-HSO ratio of 30:1, time of 2 min, heating power of 150 W, and H2SO4 dosage of 1.5 wt%. For the transesterification of WCO-HSO blend, the optimum values are methanol/WCO-HSO ratio of 6:1, time of 1 min, heating power of 450 W, and KOH dosage of 1.75 wt% with a biodiesel yield of 99.4 wt%; methanol/WCO-HSO ratio of 6:1, time of 1 min, heating power of 300 W, and calcined Ba(OH)2 dosage of 1.75 wt% with a biodiesel yield of 98.8 wt%; and methanol/WCO-HSO ratio of 6:1, time of 4 min, heating power of 450 W, and CBW dosage of 1.75 wt% with a biodiesel yield of 100 wt%. The processes catalyzed with synthetic KOH and Ba(OH)2 reached maximum biodiesel yield faster than the crude CBW. The biodiesel quality obtained in this study shows that all three fuels met the American standard specifications and could thus serve as substitutes for fossil diesel.
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    Optimization of media components and fermentation conditions for citric acid production from sweet potato peel starch hydrolysate by Aspergillus niger
    (2020) Aboyeji OO; Oloke JK; Arinkoola AO; Oke MA; Ishola MM
    This study investigated sweet potato peel waste as the main carbon source and determine the effect of media components and operating conditions on citric acid (CA) production by Aspergillus niger under submerged fermentation. The sweet potato peel waste is of low-cost readily-available and serve as hydrolysate for CA production. Two sets of experiments were performed using experimental design technique. The first set was designed using a low resolution 2-level factorial which was deployed for parameter screening. The other set of experiments was designed using 3-level design algorithm and was deployed for model development and optimization. The results from parameter screening showed that carbon source (CS), nitrogen concentration (NC), fermentation time (FT) and pH were the “heavy hitters” with significant impact on CA production. The developed model is predictive (R2 = 0.948) with optimum CA (3.22 mg/mL) obtained at CS (97.25%), NC (1.25%w/v), FT (7 days), and pH (6.5). This setting was validated experimentally and resulted in CA yield of 4.36 ± 006 mg/ml, representing a 135%-fold increase over the predicted yield. The present investigation shows that sweet potato peels hydrolysate is a viable and sustainable substrate for CA production.